The law states that the tangent of the angle at which polarization is obtained by reflection is numerically equal to the refractive index of the medium.
μ = tan θB
At Brewster's angle, reflected light is 100% polarized ⊥ to the plane of incidence.
θ_B = arctan(μ)
Polarized sunglasses block horizontally polarized light (glare from roads/water). They work best when you tilt your head ~55–60° — close to Brewster's angle for glass/water!